Product ID:17038 BLACK GLOSS ZENTHANE PLUS MIL-PRF-85285C (I)
MSDS Date:06/08/1999
FSC:8010
NIIN:01-441-6111
Status Code:A
MSDS Number: CLMYR

HENTZEN COATINGS INC

6937 WEST MILL ROAD
MILWAUKEE, WI 53218
US

Emergency Phone: 800-424-9300

Info Phone: 414-353-4200

Preparer: ERNEST CARTER

Cage: 09225

HENTZEN COATINGS INC

18749 MILWAUKEE, WI 53218 US

Telephone: 414-353-4200

Cage: 09225

CARBON BLACK

CAS: 1333-86-4

RTECS: FF5800000

OSHA PEL 3.5 MG/M3

ACGIH TLV: 3.5 MG/M3

HOMOPOLYMER OF HEXAMETHYLENE DIISOCYANATE

CAS: 28182-81-2

RTECS: NQ9170000

METHYL PROPYL KETONE

CAS: 107-87-9

RTECS: SA7875000

OSHA PEL 700 MG/M3;200 PPM

ACGIH TLV: 705 MG/M3;200 PPM

HEXAMETHYLENE DIISOCYANATE MONOMER

CAS: 822-06-0

RTECS: MO1740000

ACGIH TLV: 0.034 MG/M3;.005 PPM

1,2,4-TRIMETHYLBENZENE

CAS: 95-63-6

RTECS: DC3325000

AROMATIC HYDROCRBONS

CAS: 64742-95-6

RTECS: WF3400000

METHOXYPROPANOL ACETATE

CAS: 108-65-6

RTECS: AI8925000

METHYL AMYL KETONE

CAS: 110-43-0

RTECS: MJ5075000

OSHA PEL 465 MG/M3;100 PPM

ACGIH TLV: 233 MG/M3;50 PPM

Health Hazards Acute and Chronic:HARMFUL IF INHALED. MAY CAUSE THE
FOLLOWING EFFECTS: NOSE, THROAT AND RESPIRATORY TRACT IRRITATION,
ALLERGIC RESPIRATORY REACTION. MAY CAUSE LUNG DAMAGE. EYE AND SKIN
IRRITATION. ALLERGIC SKIN REACTIO N.
Effects of Overexposure:EYE CONTACT: ACUTE EYE CONTACT WITH LIQUID,
AEROSOLS AND VAPORS CAN BE IRRITATING CAUSING TEARING, REDDENING
ANS SWELLING ACCOMPANIED BY A STINGING AND/OR A FEELING LIKE THAT
OF FINE DUST IN THE EYES . SKIN CONTACT: REPEATED OR PROLONGED SKIN
CONTACT WITH SOLVENTS CAN CAUSE DEFATTING OF THE OF THE SKIN WHICH
CAN DEVELOP INTO DERMATITIS.INHALATION: CAN CAUSE IRRITATION OF THE
RESPIRATORY TRACT OR A CUTE NERVOUS SYSTEM DEPRESSION
CHARACTERIZED. INGESTION: SYMPTOMS CAN INCLUDE SORE THROAT,
ABDOMINAL PAIN, NAUSEA, VOMITING AND DIARRHEA.
Medical Cond Aggravated by Exposure:ASTHMA AND OTHER RESPIRATORY
AILMENTS; SKIN ALLERGIES AND ECZEMA; CHEMICAL SENSITIZATION.

First Aid:EYE CONTACT: FLUSH IMMEDIATELY WITH LOW PRESSURE LUKEWARM
RUNNING WATER FOR AT LEAST 15 MINUTES WHILE LIFTING EYELIDS.TAKE TO
A PHYSICIAN FOR TREATMENT. SKIN CONTACT:REMOVE CONTAMINATED
CLOTHING IMMED IATELY. WASH AFFECTED AREAS THOROUGHLY WITH SOAP AND
WATER. GET MEDICAL ATTENTION.INHALATION: MOVE TO AN AREA FREE
FROM RISK OF FURTHER EXPOSURE.ADMINISTER OXYGEN OR ARTIFICIAL
RESPIRATION AS NEEDED . OBTAIN MEDICAL ATTENTION. INGESTION:
CALL A PHYSICIAN IMMEDIATELY. DO NOT INDUCE VOMITING

Flash Point Method:TCC
Flash Point:=7.8C, 46.F
Lower Limits:.9
Upper Limits:8.7
Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, FOAM OR ALCOHOL FOAM.
Fire Fighting Procedures:FULL PROTECTIVE EQUIPMENT INCLUDING
SELF-CONTAINED BREATHING APPARATUS SHOULD BE WORN.DURING A FIRE,
IRRITATING AND HIGHLY TOXIC GASES AND SMOKE ARE PRESENT FROM THE
DECOMPOSITION/COMBUSTION PRODUCTS. KEEP CONTAINERS TIGHTLY CLOSED.
ISOLATE FROM HEAT, ELECTRICAL EQUIPMENT, SPARKS AND OPEN FLAMES.
Unusual Fire/Explosion Hazard:CLOSED CONTAINER MAY EXPLODE WHEN EXPOSED
TO EXTREME HEAT OR BURST WHEN CONTAMINATED WITH WATER (CARBON
DIOXIDE RELEASED). DO NOT APPLY TO HOT SURFACES. NEVER USE WELDING
OR CUTTING TORCH ON OR NEAR P RODUCT CONTAINER (EVEN EMPTY) BECAUSE
PRODUCT (EVEN RESIDUE) CAN IGNITE EXPLOSIVELY.

Spill Release Procedures:COVER SPILL WITH INERT ABSORBENT. POUR LIQUID
DECONTAMINANT OVER SPILLAGE. ALLOW TO REACT FOR AT LEAST 10
MINUTES. COLLECT MATERIAL IN OPEN CONTAINERS AND ADD FURTHER
AMOUNTS OF DECONTAMINATION SOLUTI ON. EVACUATE NONESSENTIAL
PERSONNEL. DO NOT ALLOW INTO DRAINS. REMOVE ALL SOURCES OF
IGNITION.
Neutralizing Agent:CONCENTRATED AMMONIA (3-8%), DETERGENT (2%), AND
WATER (90-95%) OR A SOLUTION OF UNION CARBIDE TERGITOL TMN-10 (

Handling and Storage Precautions:PRECAUTIONS MUST BE TAKEN SO THAT
PERSONS HANDLING THIS PRODUCT DO NOT BREATHE THE VAPORS OR HAVE IT
CONTACT THE EYES OR SKIN. STORAGE: DO NOT STORE ABOVE 120 F OR
BELOW 32 F. STORE LARGE QUANTITIES I N BUILDINGS DESIGNED TO COMPLY
WITH OSHA?S 29 CFR 1910.106.

Respiratory Protection:THE SURGEON GENERAL REQUIRES AIRLINE RESPIRATORS
TO BE USED UNLESS AIR SAMPLING SHOWS EXPOSURE TO BE BELOW OSHA
LIMITS, THEN EITHER AIR-PURIFYING CHEMICAL CARTRIDGE RESPIRATORS OR
AIRLINE RESPIRATORS ARE REQUIRED. THE SAME PRECAUTIONS SHOULD BE
USED DURING MIXING OR ANY OPERATIONS WHERE PAINT FUMES WOULD BE
PRESENT.
Ventilation:EXHAUST VENTILATION SUFFICIENT TO KEEP THE AIRBORNE
CONCENTRATIONS OF THE ISOCYANATES BELOW THEIR RESPECTIVE EXPOSURE
LIMITS MUST BE UTILIZED.
Protective Gloves:PERMEATION RESISTANT GLOVES.
Eye Protection:USE SAFETY EYEWEAR WITH SPLASH GUARDS OR SIDE SHIELDS.
Other Protective Equipment:SAFETY SHOWERS AND EYE WASH STATIONS SHOULD
BE AVAILABLE.
Work Hygienic Practices:NONE
Supplemental Safety and Health
MEDICAL SURVEILLANCE: PERSONS WITH ASTHMA-TYPE CONDITIONS, BRONCHITIS,
OTHER CHRONIC RESPIRATORY DISEASES OR RECURRENT SKIN ECZEMA OR
SENSITIZATION SHOULD BE EXCLUDED FROM WORKING WITH ISOCYANATES.

Boiling Pt:B.P. Text:LO-213.0 HI-418.0 F
Vapor Pres:27.80
Vapor Density:4.80
Spec Gravity:.993
VOC Pounds/Gallon:415
VOC Grams/Liter:3.46
Evaporation Rate & Reference:2.300
Solubility in Water:REACTS WITH WATER
Appearance and Odor:OPAQUE LIQUID SOLVENT ODOR
Percent Volatiles by Volume:49.5393

Stability Indicator/Materials to Avoid:YES
CONTAMINATION WITH WATER, EPOXY CATALYSTS, ALCOHOLS, GLYCOL ETHERS,
BASES, METAL COMPLEXES OR OTHER ACTIVE MATERIALS. ONCE THE MATERIAL
IS EXPOSED TO ABOVE OR TO MOISTURE DO NOT RESEAL AS CARBON DIOXIDE
CAN BUILD UP IN CONT
Hazardous Decomposition Products:MAY PRODUCE HAZARDOUS FUMES WHEN
HEATED TO DECOMPOSITION AS IN WELDING: CARBON MONOXIDE, CARBON
DIOXIDE, CHLORINE, HYDROGEN CHLROIDE, POSSIBLE CYANIDE,
HEXAMETHYLENE DIISOCYANATE.
Conditions to Avoid Polymerization:WILL NOT OCCUR.

Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH APPLICABLE LAWS
AND REGULATIONS.

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Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Transport Information:AS AN " ARTICLE" THIS PRODUCT IS EXCLUDED FROM
ANY REQUIREMENTS OF THE STANDARD. THIS IMPLIES THAT BATTERY MEETS
REQUIREMENTS OF REGULATIONS UNDER 49 CFR 173.159(D) AND REQUIRES
THAT BATTERIES BE PROT ECTED AGAINST SHORT CIRCUITS AND SECURELY
PACKAGED AND THE BATTERY AND OUTER PACKAGING PLAINLY AND DURABLY
MARKED "NONSPILLABLE" OR "NONSPILLABLE BATTERY". ALSO THE BATTERIES
MUST BE CAPABLE OF WITHST ANDING , WITHOUT LEAKAGE OF BATTERY
FLUID, THE VIBRATION TEST AND THE PRESSURE DIFFERENTIAL TEST
SPECIFIED IN 49 CFR 173.159(D)(3)(I) AND (I I).